Monday, September 13, 2021

Hydrogen-Like Continuum Eigenstates

 


The positive-energy continuum states of a hydrogen-like system are described by the eigenfunctions with corresponding eigenvalues , (). are the same spherical harmonics that occur for the bound states. In atomic units , the radial equation can be written . The solutions with the appropriate analytic and boundary conditions have the form . These functions are deltafunction-normalized, such that . They have the same functional forms (apart from normalization constants) as the discrete eigenfunctions under the substitution .

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Contributed by: S. M. Blinder (March 2011)
Open content licensed under CC BY-NC-SA


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Reference: H. A. Bethe and E. E. Salpeter, Quantum Mechanics of One- and Two-Electron Atoms, New York: Academic Press, 1957, pp. 21–25.


 

https://demonstrations.wolfram.com/HydrogenLikeContinuumEigenstates/ 

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